2017
Visible-Light-Promoted AuI to AuIII Oxidation in Triazol-5-ylidene Complexes, Daniel Mendoza-Espinosa, David Rendon-Nava, Alejandro Alvarez-Hernandez, Deyanira Angeles-Beltran, Guillermo E. Negron-Silva, and Oscar R. Suarez-Castillo, Chem. Asian J. 2017, 12, 203 - 207
Abstract
Reaction of triazolium precursors [MIC(CH2)n? H+]I? (n=1?3) with potassium hexamethyldisilazane (KHMDS) and AuCl(SMe2) generates the gold(I) complexes of the type MIC(CH2)n?AuI. Visible light exposure of the latter complexes promotes a spontaneous disproportionation process rendering gold(III) complexes of the type [{MIC(CH2)n}2?AuI2]+I?. Both the AuI and AuIII complex series were tested in the catalytic hydrohydrazination of terminal alkynes using hydrazine as nitrogen source.
Stereoselective addition of allylmagnesium chloride to the CN bond of [4.3.0] boron heterobicycles
Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reaction
Synthesis and Structures of some Lithium and Sodium (Aminoalcoholato)hydrido Aluminates
Structural studies of spiroarsoranes derived from 2-aminophenols
Aroylthioureas: new organic ionophores for heavy-metal ion selective electrodes
Preparation of N-aryl-substituted spiro-?-lactams via Staudinger cycloaddition
Et3B, an Efficient Mediator for Xanthate Transfer Based Radical Processes