Producción Científica Profesorado

Diastereomeric C-glycosyloxanthrones from picramnia antidesma



Rojas Lima, Susana

1999

María del Rosario Hernández-Medel, Claudia O. Ramírez-Corzas, M. Nalleli Rivera-Domínguez, Julieta Ramírez-Mendez, Rosa L. Santillan Baca and Susana Rojas-Lima, Diastereomeric C-glycosyloxanthrones from Picramia antidesma, Phytochemistry, 50, 1379-1383 (1999). DOI: http://dx.doi.org/10.1016/S0031-9422(98)00354-9


Abstract


Nine compounds were isolated and identified from the stem of Picramnia antidesma. Two of the isolated compounds: mayoside and saroside, which is new, are diastereoisomeric oxanthrones. The structure of saroside has been obtained on the basis of spectroscopic evidence. The absolute configuration of this diastereoisomeric pair has been determined by CD spectra, and that of saroside was further established by X-ray crystallographic analysis.



Producto de Investigación




Artículos relacionados

Preparation of Seven- and Eight-Membered Boron Heterocycles from Different Salen Ligands and Arylbor...

Synthesis, crystal structures, and quadratic nonlinear optical properties in a series of pushpull bo...

Addition reaction of benzylbenzylidenenamine to lithium enolates of 1,3-dioxolan-4-one: synthesis of...

Synthesis of New Chiral Derivatives of N,N?-Dimethylpropyleneurea (DMPU) and Examination of Their In...

r-Alkylation of (S)-Asparagine with Self-Regeneration of the Stereogenic Center: Enantioselective Sy...

Preparation of N-aryl-substituted spiro-?-lactams via Staudinger cycloaddition

Furocoumarins of three species of the genus Dorstenia

Structure-Activity Relationships for Inhibition of Cysteine Protease Activity and Development of Pla...

New boronates prepared from 2,4-pentanedione derived ligands of the NO2 and N2O2 type comparison to...

Synthesis and Structures of some Lithium and Sodium (Aminoalcoholato)hydrido Aluminates