Producción Científica Profesorado

trans-Bis[2-(aminomethyl)-1H-benzimidazole-2N2,N3]aquacopper(II) dichloride dihydrate



Tlahuextl Romero, Angela Margarita

2007

Hugo Tlahuext, Margarita Tlahuextl, Sandra López-Gámez, Antonio R Tapia-Benavides*, Trans-bis[2-(aminomethyl)-1H-bencimidazole-k2N2,N3]aquacopper(II) dichloride dihydrate, Acta Crystallographica E, E63, m1263-m1265 (2007)


Abstract


In the title compound, [Cu(C8H9N3)2(H2O)]Cl22H2O, the CuII ion is coordinated in a square-pyramidal geometry, with four N atoms as basal ligands and one water O atom as an apical ligand. The complex molecule is situated on a crystallographic twofold rotation axis. The molecules are bonded to their neighbours by N-HO, O-HCl and N-HCl hydogen bonds. The packing is further stabilized by - interactions between the substituted imidazole molecules.



Producto de Investigación




Artículos relacionados

Synthesis of Zn compounds derived from 1H-benzimidazol-2-ylmethanamine

Chlorination reactions of ephedrines revisited. Stereochemistry and functional groups effect on the ...

1 H, 13C, 15N, 2D and variable temperature NMR study of the role of hydrogen bonding in the structur...

Coordination chemistry of iminodiacetic esters. Structural and spectroscopic characterization of cop...

SYNTHESES, NMR STUDY AND STEREOCHEMISTRY OF NEW P-H TRICYCLOPHOSPHORANES

Crystal structure, ferromagnetostructural behavior and evidence of cooperative JahnTeller interactio...

Addition reactions of protonic reagents to optically active 2-phenyl-1,3,2-oxazaborolines

Do Spiroarsoranes Exhibit Polytopal Equilibrium in Solution?

Speciation of the new ligand di-isopropyliminodiacetoamide with Cu(II) using computational processin...

SYNTHESIS OF NOVEL DINUCLEAR COMPLEXES OF Fe(O) DERIVED FROM 1,2-DICARBONYLIC MONOHYDRAZONES