Producción Científica Profesorado

trans-Bis[2-(aminomethyl)-1H-benzimidazole-2N2,N3]aquacopper(II) dichloride dihydrate



Tlahuextl Romero, Angela Margarita

2007

Hugo Tlahuext, Margarita Tlahuextl, Sandra López-Gámez, Antonio R Tapia-Benavides*, Trans-bis[2-(aminomethyl)-1H-bencimidazole-k2N2,N3]aquacopper(II) dichloride dihydrate, Acta Crystallographica E, E63, m1263-m1265 (2007)


Abstract


In the title compound, [Cu(C8H9N3)2(H2O)]Cl22H2O, the CuII ion is coordinated in a square-pyramidal geometry, with four N atoms as basal ligands and one water O atom as an apical ligand. The complex molecule is situated on a crystallographic twofold rotation axis. The molecules are bonded to their neighbours by N-HO, O-HCl and N-HCl hydogen bonds. The packing is further stabilized by - interactions between the substituted imidazole molecules.



Producto de Investigación




Artículos relacionados

New 3,3?[2,2?-oxy-bis-(oxazaborolidine)]-ethylenes. Structural studies by NMR, X-ray, and quantum ch...

Structural study and antioxidant activity determination of (2E)-N-[2-(morpholin-4-yl)ethyl]-cinnamid...

SYNTHESES, NMR STUDY AND STEREOCHEMISTRY OF NEW P-H TRICYCLOPHOSPHORANES

Three-center intramolecular hydrogen bonding in oxamide derivatives. NMR and X-ray diffraction study

Synthesis and structural studies of N-(p-toluenesulfonyl)-amino acid 3,5-di-tert-butyl-2-phenolamide...

New 3,3?[2,2?-oxy-bis-(oxazaborolidine)]-ethylenes. Structural studies by NMR, X-ray, and quantum ch...

trans-Bis[2-(aminomethyl)-1H-benzimidazole-2N2,N3]aquacopper(II) dichloride dihydrate

Synthesis and structural studies of new N-(p-toluenesulfonyl)amino acid o-phenolamides

Chlorination reactions of ephedrines revisited. Stereochemistry and functional groups effect on the ...

Acid-base equilibrium studies of 2-(aminomethyl)benzimidazolein aqueous solution