Producción Científica Profesorado

Synthesis of 3-Arylpyrroles and 3-Pyrrolylacetylenes by Palladium-Catalyzed Coupling Reactions



Alvarez Hernandez, Alejandro

1992

Alvarez Hernández A.; Guzmán A.; Ruiz, A.; Velarde, E.; Muchowski J. M. Synthesis of 3-Arylpyrroles and 3-Pyrrolylacetylenes by Palladium-Catalyzed Coupling Reactions. Journal of Organic Chemistry, 1992, 57, 1653-1656. ISSN 0022-3263. The American Chemical Society, Washington, Estados Unidos de América.


Abstract


Efficacious methods for the synthesis of 3-arylpyrroles or 3-pyrrolylacetylenes are described based on the palladium-catalyzed coupling of appropriate 1-(triisopropylsilyl)-3-substituted pyrroles with aryl halides or monosubstituted acetylenes and subsequent tetrabutylammonium fluoride desilylation.






Artículos relacionados

A flexible access to highly functionalised boronates

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

Preparation of N-aryl-substituted spiro-?-lactams via Staudinger cycloaddition

ChemInform Abstract: Facile Preparation of [4.4]Metacyclophane- and [5.5]Paracyclophane-Type Macrocy...

New boronates prepared from 2,4-pentanedione derived ligands of the NO2 and N2O2 type comparison to...

An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicy...

Bis(acetylsalicylato-j2O,O00)diaquacadmium(II)

Effect of TiO2Al2O3 SolGel Supports on the Superficial Ni and Mo Species in Oxidized and Sulfided Ni...

Ylidaddukte der Penteltrichloride

Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reactio