Producción Científica Profesorado

Synthesis of 3-Arylpyrroles and 3-Pyrrolylacetylenes by Palladium-Catalyzed Coupling Reactions



Alvarez Hernandez, Alejandro

1992

Alvarez Hernández A.; Guzmán A.; Ruiz, A.; Velarde, E.; Muchowski J. M. Synthesis of 3-Arylpyrroles and 3-Pyrrolylacetylenes by Palladium-Catalyzed Coupling Reactions. Journal of Organic Chemistry, 1992, 57, 1653-1656. ISSN 0022-3263. The American Chemical Society, Washington, Estados Unidos de América.


Abstract


Efficacious methods for the synthesis of 3-arylpyrroles or 3-pyrrolylacetylenes are described based on the palladium-catalyzed coupling of appropriate 1-(triisopropylsilyl)-3-substituted pyrroles with aryl halides or monosubstituted acetylenes and subsequent tetrabutylammonium fluoride desilylation.






Artículos relacionados

Synthesis of new homochiral 2,3-dialkylpiperazines derived from (R)-(?)-phenylglycinol

A flexible access to highly functionalised boronates

Bis(acetylsalicylato-j2O,O00)diaquacadmium(II)

Facile synthesis of 1,3,6-oxadiazepines from 2,2?-(1,2-ethanediyldiimino)bisphenols

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

Ylidaddukte der Penteltrichloride

Cathepsins X and B Can Be Differentiated through Their Respective Mono- and Dipeptidyl Carboxypeptid...

A practical access to acyl radicals from acyl hydrazides

Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reaction

Enantioselective synthesis of ?-amino acids. Part 11: Diastereoselective alkylation of chiral deriva...