Producción Científica Profesorado

Synthesis of 3-Arylpyrroles and 3-Pyrrolylacetylenes by Palladium-Catalyzed Coupling Reactions



Alvarez Hernandez, Alejandro

1992

Alvarez Hernández A.; Guzmán A.; Ruiz, A.; Velarde, E.; Muchowski J. M. Synthesis of 3-Arylpyrroles and 3-Pyrrolylacetylenes by Palladium-Catalyzed Coupling Reactions. Journal of Organic Chemistry, 1992, 57, 1653-1656. ISSN 0022-3263. The American Chemical Society, Washington, Estados Unidos de América.


Abstract


Efficacious methods for the synthesis of 3-arylpyrroles or 3-pyrrolylacetylenes are described based on the palladium-catalyzed coupling of appropriate 1-(triisopropylsilyl)-3-substituted pyrroles with aryl halides or monosubstituted acetylenes and subsequent tetrabutylammonium fluoride desilylation.






Artículos relacionados

Structural studies of spiroarsoranes derived from 2-aminophenols

Synthesis of New Chiral Derivatives of N,N?-Dimethylpropyleneurea (DMPU) and Examination of Their In...

Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reactio

Phenylmethyl 2,3,4-tri-O-acetyl--D-fucopyranoside

Synthesis and Study of Isomeric Benzo[1,4]oxazines and Benzothiazolines by NMR Spectroscopy and X-Ra...

3-Benzoyl-2-isopropyl-4-alkyloxazolidin-5-ones as Efficient and Inexpensive Sources of Enantiopure ?...

Enantioselective synthesis of ?-amino acids. Part 11: Diastereoselective alkylation of chiral deriva...

Enantioselective synthesis of ?-amino acids. Part 10: Preparation of novel ?,?- and ?,?-disubstitute...

An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicy...

ChemInform Abstract: Facile Preparation of [4.4]Metacyclophane- and [5.5]Paracyclophane-Type Macrocy...