Producción Científica Profesorado

Electrochemical Determination of Pb(II) Using Carbon Paste Electrodes Modified with Ion Imprinted Polymers (IIPs).



Galan Vidal, Carlos Andres

2022

Luz E. Rebolledo, Giaan Arturo Álvarez Romero, Israel Samuel Ibarra-Ortega, Carlos Andres Galan-Vidal, Irma Pérez-Silva. (2022). Electrochemical Determination of Pb(II) Using Carbon Paste Electrodes Modified with Ion Imprinted Polymers (IIPs). ECS Transactions, 106, 21.


Abstract


An easy, low-cost, and highly selective carbon paste electrode based on an ion-imprinted polymer (IIP) to determine Pb(II) in real samples was developed. The recognition cavities based on a cross-linked polymer selective to Pb(II) were created using vinyl pyridine. The modified CPE was constructed by a composite mixture with the synthesized IIP. A notable difference was observed in the electrochemical response of the electrodes modified with the IIP and a non-imprinted polymer, demonstrating the unique properties of the IIP recognition sites. The parameters related to the current intensity were optimized; the selectivity was also studied considering potential interference ions. The proposed modified electrode demonstrated to be as (or more) selective to Pb(II) compared to others previously reported in the literature. A linear concentration range from 3.3 mg/L to 33 mg/L with a limit detection of 1 mg/L was obtained. The Pb(II) preconcentrated on the electrode surface was successfully quantified in real potable water samples without previous treatment.






Artículos relacionados

Revisión de variables de diseño y condiciones de operación en la electrocoagulación

Mercury Ions Removal from Aqueous Solution Using an Activated Composite Membrane

Potentiometric behavior of graphite-epoxy electrochemical transducers towards anions, cations and pH...

Kinetics of Polypyrrole Films Doped with Sulphate Ions Electrodeposited Over Graphite - Epoxy Resin ...

Quantum chemical study of the electrochemical reduction of the [Co(H2O)6]2+ and [Co(NH3)5(H2O)]2+ io...

Do Spiroarsoranes Exhibit Polytopal Equilibrium in Solution?

Analysis of the experimental pressuretemperature behavior in the isotropicnematic phase transition f...

Hydrogen bond studies in substituted N-(2-hydroxyphenyl)--2-[(4-methylbenzenesulfonyl)amino]acetamid...

Synthesis of Zn compounds derived from 1H-benzimidazol-2-ylmethanamine

Chemical Reactivity of Atrazine Employing the Fukui Function