2012
Ung, G.; Mendoza-Espinosa, D.; Bertrand G. Novel Route to Ynamides: Stable Ligands Equivalent to Unstable Oxazol-4-Ylidenes. Chem. Commun. 2012, 48, 7088-7090.
Abstract
Deprotonation of an oxazolium salt induces a ring opening process leading to the corresponding ynamide. Although the expected mesoionic carbene is not obtained, the acyclic ynamide readily reacts with various transition metals yielding robust mesoionic carbene complexes.
Transesterifications mediated by t-BuNH2
Stereochemical assignment of naturally occurring 2,3-epoxy-2-methylbutanoate esters
Synthesis of Bromoindole Alkaloids from Laurencia brongniartii
Configuration, stereodynamics and crystal structure of 3-substituted-2-oxofuro[2,3-b]indoles
Aromatic Bromination versus Oxidation of Indolylmalonates by Bromine
Absolute configuration determination of 2-(2-oxo-3-indolyl)acetamide derivatives
The absoluteconfiguration of cuauhtemone and related compounds