Expedient synthesis of highly functionalized abnormal gold complexes.
Mendoza Espinosa, Daniel
2018
Flores-Jarillo, M.; Salazar-Pereda, V.; Ruiz-Mendoza, F. J.; Álvarez-Hernández, A.; Mendoza-Espinosa, D.*Expedient synthesis of highly functionalized abnormal gold complexes. Inorg. Chem. 2018, 57, 28-31.
Abstract
The reaction of 4-substituted imidazol-2-ylidenes with various electrophiles produces a series of 2,4-functionalized imidazolium salts. Subsequent metalation of these precursors using AuCl(SMe2) provides the first examples of highly functionalized abnormal carbenegold(I) complexes. The present protocol introduces a new strategy for the synthesis of metallic abnormal carbenes featuring diverse functional groups
Artículos relacionados
Conformational studies on indole alkaloids from Flustra foliacea by NMR and molecular modeling
13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters
One-potsynthesis of conformationallyrestrictedspirooxindoles
Synthesis of Bromoindole Alkaloids from Laurencia brongniartii
Cleavage of alkoxycarbonyl protecting groups from carbamates by t-BuNH2
Trapping enols of esters and lactones with diazomethane