2017
Visible-Light-Promoted AuI to AuIII Oxidation in Triazol-5-ylidene Complexes, Daniel Mendoza-Espinosa, David Rendon-Nava, Alejandro Alvarez-Hernandez, Deyanira Angeles-Beltran, Guillermo E. Negron-Silva, and Oscar R. Suarez-Castillo, Chem. Asian J. 2017, 12, 203 - 207
Abstract
Reaction of triazolium precursors [MIC(CH2)n? H+]I? (n=1?3) with potassium hexamethyldisilazane (KHMDS) and AuCl(SMe2) generates the gold(I) complexes of the type MIC(CH2)n?AuI. Visible light exposure of the latter complexes promotes a spontaneous disproportionation process rendering gold(III) complexes of the type [{MIC(CH2)n}2?AuI2]+I?. Both the AuI and AuIII complex series were tested in the catalytic hydrohydrazination of terminal alkynes using hydrazine as nitrogen source.
Synthesis of Bromoindole Alkaloids from Laurencia brongniartii
Total Syntheses of Five Indole Alkaloids from the Marine Bryozoan Flustra foliacea
Unimolecular rearrangements of ketene-O,O-acetals and fragmentations occurring in the gas phase
13C NMR and crystallographic evidence of push-pull effects in furoindolic ?-enamino esters
The absoluteconfiguration of cuauhtemone and related compounds
Absolute configuration determination of 2-(2-oxo-3-indolyl)acetamide derivatives
First Total Synthesis of ()-Flustraminol B
Role of lipid peroxidation in biliary obstruction in the rat
Aromatic Bromination versus Oxidation of Indolylmalonates by Bromine