2017
Visible-Light-Promoted AuI to AuIII Oxidation in Triazol-5-ylidene Complexes, Daniel Mendoza-Espinosa, David Rendon-Nava, Alejandro Alvarez-Hernandez, Deyanira Angeles-Beltran, Guillermo E. Negron-Silva, and Oscar R. Suarez-Castillo, Chem. Asian J. 2017, 12, 203 - 207
Abstract
Reaction of triazolium precursors [MIC(CH2)n? H+]I? (n=1?3) with potassium hexamethyldisilazane (KHMDS) and AuCl(SMe2) generates the gold(I) complexes of the type MIC(CH2)n?AuI. Visible light exposure of the latter complexes promotes a spontaneous disproportionation process rendering gold(III) complexes of the type [{MIC(CH2)n}2?AuI2]+I?. Both the AuI and AuIII complex series were tested in the catalytic hydrohydrazination of terminal alkynes using hydrazine as nitrogen source.
Conformational studies on indole alkaloids from Flustra foliacea by NMR and molecular modeling
One-potsynthesis of conformationallyrestrictedspirooxindoles
Regioselective Synthesis of 3-Indolyl(alkoxy)acetates
Unimolecular rearrangements of ketene-O,O-acetals and fragmentations occurring in the gas phase
Synthesis of Bromoindole Alkaloids from Laurencia brongniartii
Synthesis of 6-bromo-2-arylindoles using 2-iodobenzoic acid as precursor
Absolute configuration determination of 2-(2-oxo-3-indolyl)acetamide derivatives
Role of lipid peroxidation in biliary obstruction in the rat