Producción Científica Profesorado

Synthesis and Catalytic Benefits of Tetranuclear Gold(I) Complexes with a C4 Symmetric Tetratriazol-5-ylidene



González Montiel, Simplicio

2017

Synthesis and Catalytic Benefits of Tetranuclear Gold(I) Complexeswith a C4?Symmetric Tetratriazol-5-ylideneMariana Flores-Jarillo, Daniel Mendoza-Espinosa,* Verónica Salazar-Pereda, Simplicio González-Montiel, Organometallics, 2017doi:10.1021/acs.organomet.7b00712


Abstract


The facile preparation of a C4-symmteric tetratriazolium salt and its subsequent metalation to generate a series of tetranuclear mesoionic carbene gold(I) complexes is presented. The complete structural characterization of the metallic carbenes and the benefits of cooperative catalysis in the processes of hydroamination and hydrohydrazination of terminal alkynes are discussed.



Producto de Investigación



Artículos relacionados

Benzazole-N(SINGLE BOND)BH3 adducts. Reductive transposition of 2-benzimidazole, 2-benzothiazole, an...

Pentacoordination at antimony in dibenzostibocines via DSb transannular interactions (D = O, S): A s...

Synthesis, Characterisation and Properties of As-Monohalogenated Dibenzoarsocines S(C6H4S)2AsHal (Ha...

Hexacoordinated spirocyclic germanium(IV) complex: Synthesis and structural characterization

Synthesis, Characterisation and Properties of As-Monohalogenated Dibenzoarsocines S(C6H4S)2AsHal (Ha...

Pentacoordination at Germanium by Transannular Bonding of Sulfur or Oxygen in an Eight-Membered Ring...

Six-membered ring chelate complexes of Pd(II) and Pt(II) derived from di-(2-pyridyl)pyrimidin-2-ylsu...

Five-membered ring chelate complexes of Ni(II), Pd(II) and Pt(II) derived of di-(2-pyridyl)-N-ethyli...

Synthesis, characterization and crystal structures of organolead dithiolate compounds displaying tra...

Study of the D?Sb (D = O, S) Transannular Interaction in Sb-Monohalogenated Dibenzostibocines ? An E...