Producción Científica Profesorado

Synthesis and Catalytic Benefits of Tetranuclear Gold(I) Complexes with a C4 Symmetric Tetratriazol-5-ylidene



González Montiel, Simplicio

2017

Synthesis and Catalytic Benefits of Tetranuclear Gold(I) Complexeswith a C4?Symmetric Tetratriazol-5-ylideneMariana Flores-Jarillo, Daniel Mendoza-Espinosa,* Verónica Salazar-Pereda, Simplicio González-Montiel, Organometallics, 2017doi:10.1021/acs.organomet.7b00712


Abstract


The facile preparation of a C4-symmteric tetratriazolium salt and its subsequent metalation to generate a series of tetranuclear mesoionic carbene gold(I) complexes is presented. The complete structural characterization of the metallic carbenes and the benefits of cooperative catalysis in the processes of hydroamination and hydrohydrazination of terminal alkynes are discussed.



Producto de Investigación



Artículos relacionados

cis-Palladium(II) complexes of derivatives of di-(2-pyridyl)methane: Study of the influence of the b...

Versatile behavior of 2-guanidinobenzimidazole nitrogen atoms toward protonation, coordination and m...

Structural differences in eight- and ten-membered heterocyclic tin compounds displaying transannular...

Understanding and Predicting Distorted T- versus Y-Geometries for Neutral Chromous Complexes Support...

Synthesis and crystal structures of cis-palladium(II) and cis-platinum(II) complexes containing dipy...

Organometallic tin complexes derived from 2-guanidinobenzimidazole

Synthesis, characterization and crystal structures of organolead dithiolate compounds displaying tra...

Synthesis and Crystal Structure of [Te{S(C6H3S)2O}]: A Tetracyclic Tellurium(II) Compound Displaying...

Determination of Glucose by Flow Injection Analysis with Amperometric Detection at Fe(III)-(tris(3,5...

Synthesis, characterization and crystal structures of dipyridyl-N-methylimine and cloro-bis (N,N?-2,...