Producción Científica Profesorado

Identification of Anthocyanins in Red Grape, Plum and Capulin by MALDI-ToF MS



Galan Vidal, Carlos Andres

2012

Castaneda-Ovando, A; Sedo, O; Havel, J; Pacheco, L; Galan-Vidal, CA; Lopez, EC., JOURNAL OF THE MEXICAN CHEMICAL SOCIETY, Año 2012 Volume: 56 Issue: 4 Pages: 378-383 ISSN: 1870-249X


Abstract


A simple and fast method was developed to identify anthocyanins in red grapes, plums and capulins by MALDI-ToF MS. Three different matrices were used: alpha-CHCA (alpha-cyano-4-hydroxycinnamic acid), THA (2',4',6'-trihydroxyacetophenone) and DHBA (2,5-dihydroxybenzoic acid). Post-Source Decay (PSD) fragment detection allowed studying the structure of compounds detected. Deprotonated anthocyanin species were assigned in capulin ([Cyanidin-3-glucoside-deprotonated] K+ and [Cyanidin-3-rutinoside-deprotonated]K+), due to these compounds also can be ionized in form of potassium adducts combined with a deprotonation.



Producto de Investigación




Artículos relacionados

Nucleation and Growth Kinetics of Electrodeposited Sulfate-Doped Polypyrrole: Determination of the D...

Cobalt electrodeposition onto highly oriented pyrolytic graphite (HOPG) electrode from ammonium sulf...

Cobalt electrodeposition on polycrystalline palladium. Influence of temperature on kinetic parameter...

Do Spiroarsoranes Exhibit Polytopal Equilibrium in Solution?

A Semiempirical PM6 Study of Some Aminopyrimidine Derivatives and their Interaction with an Iron Sur...

Predicting the Phase Diagram of a Liquid Crystal Using the Convex Peg Model and the Semiempirical PM...

Nucleation and growth of cobalt onto different substrates: Part II. The upd-opd transition onto a go...

Nucleation and growth of cobalt onto different substrates: Part I. Underpotential deposition onto a ...

Electrochemical kinetic study about cobalt electrodeposition onto GCE and HOPG substrates from sulfa...

Kinetic study of the cobalt electrodeposition onto glassy carbon electrode from ammonium sulfate sol...