Producción Científica Profesorado

Diastereomeric C-glycosyloxanthrones from picramnia antidesma



Rojas Lima, Susana

1999

María del Rosario Hernández-Medel, Claudia O. Ramírez-Corzas, M. Nalleli Rivera-Domínguez, Julieta Ramírez-Mendez, Rosa L. Santillan Baca and Susana Rojas-Lima, Diastereomeric C-glycosyloxanthrones from Picramia antidesma, Phytochemistry, 50, 1379-1383 (1999). DOI: http://dx.doi.org/10.1016/S0031-9422(98)00354-9


Abstract


Nine compounds were isolated and identified from the stem of Picramnia antidesma. Two of the isolated compounds: mayoside and saroside, which is new, are diastereoisomeric oxanthrones. The structure of saroside has been obtained on the basis of spectroscopic evidence. The absolute configuration of this diastereoisomeric pair has been determined by CD spectra, and that of saroside was further established by X-ray crystallographic analysis.



Producto de Investigación




Artículos relacionados

Diastereoselective alkylation of chiral glycinate derivatives containing the ?-phenylethyl group.

Preparation of N-aryl-substituted spiro-?-lactams via Staudinger cycloaddition

Aroylthioureas: new organic ionophores for heavy-metal ion selective electrodes

Further insight into three center hydrogen bonding. Participation in tautomeric equilibria of hetero...

Synthesis of nitrogen-, oxygen- and sulphur-containing tripodal ligands with a trimethylbenzene core...

New boronates prepared from 2,4-pentanedione derived ligands of the NO2 and N2O2 type comparison to...

The Structural Chemistry of N-Monolithium Borazines

Cathepsins X and B Can Be Differentiated through Their Respective Mono- and Dipeptidyl Carboxypeptid...

O-benzyl-N-(2-furoyl)thiocarbamate

Synthesis of new homochiral 2,3-dialkylpiperazines derived from (R)-(?)-phenylglycinol