Producción Científica Profesorado

O-benzyl-N-(2-furoyl)thiocarbamate



Rojas Lima, Susana

2004

Luis Alberto Montiel Ortega, Susana Rojas-Lima, Elena Otazo Sanchez, Roberto Villagómez Ibarra. O-benzyl-N-(2-furoyl)thiocarbamate. Journal of Chemical Crystallography 34, 2, 89-93 (2004). http://dx.doi.org/10.1023/B:JOCC.0000014694.33182.ff


Abstract


The O-benzyl-N-(2-furoyl)thiocarbamate (1) was obtained by direct reaction between furoyl isothiocyanate and benzyl alcohol. The X-ray diffraction analysis of 1 showed an orthorhombic system, with a = 7.811(4) Å, b = 9.685(4) Å, c = 33.562(15) Å, and space group P212121. This compound showed two different arrays of structure, corresponding to two conformers in the same crystal unit. In one conformer the carbonyl and thiocarbonyl groups are in a syn arrangement while in the other the groups are anti. Both structures present a non-restricted conformation and show NH\bondOC hydrogen bonding between them.



Producto de Investigación




Artículos relacionados

Cathepsins X and B Can Be Differentiated through Their Respective Mono- and Dipeptidyl Carboxypeptid...

Synthesis and Study of Monomeric and Dimeric Boronates by Spectroscopic Methods and X-ray Crystallog...

An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicy...

Ylidaddukte der Penteltrichloride

Bis(acetylsalicylato-j2O,O00)diaquacadmium(II)

Structural studies of spiroarsoranes derived from 2-aminophenols

Synthesis and Study of Isomeric Benzo[1,4]oxazines and Benzothiazolines by NMR Spectroscopy and X-Ra...

Effect of TiO2Al2O3 SolGel Supports on the Superficial Ni and Mo Species in Oxidized and Sulfided Ni...

Preparation of N-aryl-substituted spiro-?-lactams via Staudinger cycloaddition

Addition reaction of benzylbenzylidenenamine to lithium enolates of 1,3-dioxolan-4-one: synthesis of...