Producción Científica Profesorado

O-benzyl-N-(2-furoyl)thiocarbamate



Rojas Lima, Susana

2004

Luis Alberto Montiel Ortega, Susana Rojas-Lima, Elena Otazo Sanchez, Roberto Villagómez Ibarra. O-benzyl-N-(2-furoyl)thiocarbamate. Journal of Chemical Crystallography 34, 2, 89-93 (2004). http://dx.doi.org/10.1023/B:JOCC.0000014694.33182.ff


Abstract


The O-benzyl-N-(2-furoyl)thiocarbamate (1) was obtained by direct reaction between furoyl isothiocyanate and benzyl alcohol. The X-ray diffraction analysis of 1 showed an orthorhombic system, with a = 7.811(4) Å, b = 9.685(4) Å, c = 33.562(15) Å, and space group P212121. This compound showed two different arrays of structure, corresponding to two conformers in the same crystal unit. In one conformer the carbonyl and thiocarbonyl groups are in a syn arrangement while in the other the groups are anti. Both structures present a non-restricted conformation and show NH\bondOC hydrogen bonding between them.



Producto de Investigación




Artículos relacionados

Addition reaction of benzylbenzylidenenamine to lithium enolates of 1,3-dioxolan-4-one: synthesis of...

An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicy...

Diastereoselective Synthesis of Spiro-?-lactams via Staudinger Reactio

Aroylthioureas: new organic ionophores for heavy-metal ion selective electrodes

Et3B, an Efficient Mediator for Xanthate Transfer Based Radical Processes

Diastereomeric C-glycosyloxanthrones from picramnia antidesma

An efficient potassium cyanide-promoted synthesis of 2-arylbenzoxazoles from [4.3.0]boron heterobicy...

Furocoumarins of three species of the genus Dorstenia

Phenylmethyl 2,3,4-tri-O-acetyl--D-fucopyranoside

Addition reaction of benzylbenzylidenenamine to lithium enolates of1,3-dioxolan-4-one: synthesis of ...